Tuesday, April 7, 2009

Electroplating 4

History

Nickel plating
Modern electrochemistry was invented by Italian chemist Luigi V. Brugnatelli in 1805. Brugnatelli used his colleague Alessandro Volta's invention of five years earlier, the voltaic pile, to facilitate the first electrodeposition. Brugnatelli's inventions were repressed by the French Academy of Sciences and did not become used in general industry for the following thirty years.

By 1839, scientists in Britain and Russia had independently devised metal deposition processes similar to Brugnatelli's for the copper electroplating of printing press plates. Soon after, John Wright of Birmingham, England discovered that potassium cyanide was a suitable electrolyte for gold and silver electroplating. Wright's associates, George Elkington and Henry Elkington were awarded the first patents for electroplating in 1840. These two then founded the electroplating industry in Birmingham from where it spread around the world.

As the science of electrochemistry grew, its relationship to the electroplating process became understood and other types of non-decorative metal electroplating processes were developed. Commercial electroplating of nickel, brass, tin, and zinc were developed by the 1850s. Electroplating baths and equipment based on the patents of the Elkingtons were scaled up to accommodate the plating of numerous large scale objects and for specific manufacturing and engineering applications.

The plating industry received a big boost from the advent of the development of electric generators in the late 19th century. With the higher currents, available metal machine components, hardware, and automotive parts requiring corrosion protection and enhanced wear properties, along with better appearance, could be processed in bulk.

The two World Wars and the growing aviation industry gave impetus to further developments and refinements including such processes as hard chromium plating, bronze alloy plating, sulfamate nickel plating, along with numerous other plating processes. Plating equipment evolved from manually operated tar-lined wooden tanks to automated equipment, capable of processing thousands of kilograms per hour of parts.

One of the American physicist Richard Feynman's first projects was to develop technology for electroplating metal onto plastic. Feynman developed the original idea of his friend into a successful invention, allowing his employer (and friend) to keep commercial promises he had made but could not have fulfilled otherwise.

Electroplating is one of the three processes that form the LIGA-process used to manufacture MEMS devices.

References:
  1. http://en.wikipedia.org
  2. Dufour, IX-1.
  3. Dufour, IX-2.
  4. Dufour, IX-3.
  5. Todd, pp. 454–458.
  6. Degarmo, E. Paul; Black, J. T.; Kohser, Ronald A. (2003), Materials and Processes in Manufacturing (9th ed.), Wiley, p. 794, ISBN 0-471-65653-4.
  7. Richard Feynman, Surely You're Joking, Mr. Feynman! (1985), in chap. 6: "The Chief Research Chemist of the Metaplast Corporation"
  8. Dufour, Jim (2006). An Introduction to Metallurgy, 5th ed. Cameron.
  9. Mohler, James B. (1969). Electroplating and Related Processes. Chemical Publishing Co. ISBN 0-8206-0037-7.
  10. Todd, Robert H.; Dell K. Allen and Leo Alting (1994). "Surface Coating". Manufacturing Processes Reference Guide. Industrial Press Inc. ISBN 0-8311-3049-0. http://books.google.com/books?id=6x1smAf_PAcC.